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Q.

For the following electrochemical cell at 298K,

Pt(s)   H2(g,1bar)H+(aq,1M)   M4+(aq),M2+(aq)   Pt(s)

Ecell=0.092V when   M2+(aq)M4+(aq)=10x

Given:  EM4+/M2+0=0.151V;2.303RTF=0.059V  The value of  x  is

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a

2

b

1

c

-2

d

-1

answer is D.

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Detailed Solution

Pt,H21barH+1MM+4M+2Pt H22H++2e,   E0=0 M+4+2eM+2,   E0=0.151 H2+M+4aqu2H++M+2aqu;  E0=0.151 

E=E02.303RTFlogH+2M+2M+4 0.092=0.1512.303RT2FlogM+2aquM+4aqu0.059=2.303RT2FlogM+2M+4 0.059=0.0592FlogM+2M+4M+2M+4

=102=10xx=2

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