Q.

For the following reaction 2X+YkP the rate of reaction is dPdtkX. Two moles of X are mixed with one mole of Y to make 1.0L of solution. At 50 s, 0.2 mole of Y is left in the reaction mixture. The correct statement(s) about the reaction is (are)

(Use: ln 2=0.693) 

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a

The rate constant, k, of the reaction is 13.86×104s1

b

Half-life of X is 50s.

c

At 100s, dYdt=3.46×103molL1s1.

d

At 50s,dXdt=13.86×103molL1s1.

answer is B, C, D.

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Detailed Solution

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Rate = dpdt=kX1

2X+YP

t=0,        2 mol    1mol

t=50s,    1 mol      0.5 mol 0.5 mol

=12dXdt=dPdt=kX1

=dXdt=2kX1

k=ln2100=6.93×103s

t1/2=ln2×50ln2=50sec

At 50 sec dXdt=2k×11=ln250

=13.86×103molL1s1

At 100 sec 12dXdt=dYdt

dYdt=ln2100×12dYdt=KX1

dYdt=3.46×103molL1s1

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