Q.

For the following reaction  2x+yKP
The rate of reaction is dPdt=Kx  . Two moles of ‘x’ are mixed with one mole of ‘y’ to make 1.0 L of solution. At 50 S, 0.5 mole of ‘y’ is left in the reaction mixture? The rate constant K is  13.86×10x , x is __________.
 

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answer is 3.

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Detailed Solution

              2x            +y       kPat    t=0                  2mol              1mol                       0at   t=50  sec            22×0.5           0.5mol              0.5mol                                                 1  mol                        0.5mol               0.5molk=2.303tlogR0Rk=2.30350log21k=2.30350×0.3010=0.69350=0.01380s1=13.86×103

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