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Q.

For the following reaction:

A(g)+B(g)2C(g)+D(g)

the rate law is given as rate of disappearance A =K[A]2/3[B]1/3. If initial concentration of A and B are 2M each and no C and D were present initially, then the time at which total concentration (sum of concentrations of A, B, C and D) will become 5.5 M, is:

(Given:K=1.386×101min1)

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a

5 min

b

10 sec

c

600 sec

d

12min

answer is C.

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Detailed Solution

  A   + B   2C +  D   2         2        -        - 2x2x2xx4+x=5.5  x=1.5 1.386×101×t=ln20.5t=10min

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