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Q.

For the formation of Cr2O3 and Al2O3, values of ΔfG0 are 540 kJ mol-1 and -827 kJ mol-1 respectively. What will be the possibility for reaction of Cr2O3 by Al?

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a

Reduction of Cr2O3 by Al will take place

b

Neither oxidation nor reduction take place

c

Oxidation of Cr2O3 by Al will take place

d

Reaction is not feasible

answer is A.

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Detailed Solution

The value of ΔrG° for formation of Cr2O3 is -540kJmol-1 is higher than Al2O3 is -827 kJ mol-1. Therefore the reduction of Cr2O3 with Al is possible.

Cr2O3s+2AlsΔ2Crl+Al2O3

Hence the correct answer is (A) Reduction of Cr2O3 by Al will take place.

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