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Q.

For the gaseous reaction : A(g)Products, the rate may be expressed as

Method I : 1VdnAdt=k1CAn

Method II : dPAdt=k2PAn

where CA=nAV= molar concentration of A and pA is the partial pressure of A at time 't' and 'n' is the order of reaction. The reaction is occurring at constant temperature, T = 300 K. Assume ideal behaviour of gas. Select the correct statement(s).

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a

k1 = k2 · (RT), when n = 0

b

k1 = k2 for any value of 'n'

c

k1 = k2 , when n =1

d

k1 = k2 · (RT), when n = 2

answer is B, D.

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Detailed Solution

CA=PART;dCAdt=1RTdPAdt=k1CAndPAdt=kRTPAn(RT)n=k2PAn n=1;k1=k2 n=2;k1RT=k2

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