Q.

For the given aqueous reactions, which of the statement(s) is / are true?

Excess

KI+K3Fe(CN)6 dil. H2SO4 Brownish-yellow solution                                                      ZnSO4                     White ppt. + Brownish-yellow filtrate                                                         Na2s2O3                                           Colourless solution                  

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a

Addition of filtrate to starch solution gives blue colour.

b

White precipitate is Zn3Fe(CN)62.

c

White precipitate is soluble in NaOH solution.

d

The first reaction is a redox reaction..

answer is A, C, D.

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Detailed Solution

The solutions are,

Brownish yellow solution is K4Fe(CN)6.

White ppt is  K2ZnFe(CN)6or K2Zn3Fe(CN)62

Brownish yellow filterate is I2.

Thus, option a, c and d are correct.

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