Q.

For the given reactions Sn2++2eSnSn4++4eSn the electrode potentials are; ESn2+/SnO=0.140V and ESn4+/SnO=0.010V. The magnitude of standard electrode potential for Sn4+/Sn2+ i.e. ESn4+/Sn2+o is ___________ ×102V. (Nearest integer)

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answer is 16.

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Detailed Solution

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Sn2++2eSn      ΔG10=+2×0.140×FSn+4+4eSn      ΔG20=4×0.01×FSn+4+2eSn+2  ΔG30=2×E0Sn+4/Sn+2×F¯ΔG30=ΔG20ΔG102×E0×F=(0.04+0.28)×FE0=0.16 volt =16×102V 

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For the given reactions Sn2++2e−→Sn, Sn4++4e−→Sn the electrode potentials are; ESn2+/SnO=−0.140V and ESn4+/SnO=0.010V. The magnitude of standard electrode potential for Sn4+/Sn2+ i.e. ESn4+/Sn2+o is ___________ ×10−2V. (Nearest integer)