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Q.

For the non –stoichiometric reaction 2A+BC+D, the following kinetic data were obtained in three separate experiments, all at 298k.

Initial concentration (A)Initial concentration (B)Initial rate of formation of C  (molL1s1)
0.1M0.1M1.2×103
0.1M0.2M1.2×103
0.2M0.1M2.4×103

The rate law for the formation of C is
 

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a

dcdt=k[A|B]

b

dcdt=k[A]2[B]

c

dcdt=k[A|B]2

d

dcdt=k[A]

answer is D.

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Detailed Solution

letrateofreaction=d[c]t=k Ax By nowfromthegivendata1.2×103=k 0.1x0.1y  ...(i)1.2×103=k 0.1x0.2y.....(ii)2.4×103=k0.1x0.2y.......(iii)Dividingequation(i)and(ii)1.2×1031.2×103=k[0.1]x[0.1]yk[0.1]x[0.1]ywefind,y=0nowdividingequatin(i)by(iii)1.2×1031.2×103=k[0.1]x[0.1]yk[0.2]x[0.1]ywefindx=1Henced[C]dt=k A1 B0  

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