For the process,

${\mathrm{H}}_2\mathrm{O}(l,T\mathrm{K},P\mathrm{bar})⟶{\mathrm{H}}_2\mathrm{O}(\mathrm{g},T\mathrm{K},P\mathrm{bar})$

Identify the option which is not correct.

ΔG = −ve,

When P = vapour pressure of ${\mathrm{H}}_2\mathrm{O}$(l) at a temperature above T K.

When atmospheric pressure = vapour pressure of liquid and,

Temperature > boiling point

Then liquid spontaneously boils as well as free energy change is negative.