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Q.

For the reaction 2 A + B Products, it is found that doubling the concentration of both reactants increases the rate by a factor of 8. But doubling the concentration of B alone, only doubles the rate. What is the order of the reaction w.r.t to A ?

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a

2

b

1

c

0

d

3

answer is A.

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Detailed Solution

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When [B] is doubled keeping [A] constant ,rate doubles 

r[B]p;2r[2B]p

solving both equations, order with respect to "B", p = 1

when concentration of both are doubled rate increases by a factor of 8

r[A]q[B]p 8r[2A]q[2B]p

solving both reactions order with respect to "A" q =2

rate law =K[A]2[B]1

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