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Q.

For the reaction 2A B+3C;if dAdt=k1A2;dBdt=k2A2;dCdt=k3A2. The correct relation between k1,k2 and k3 is :

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a

k1=k2=k3

b

2k1=k2=3k2

c

4k1=k2=3k2

d

k12=k2=k33

answer is D.

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Detailed Solution

2A→B+3B

from law of chemical equilibrium

12dAdt=dBdt=13dCdt

Given  12K1A2=K2A2=K33A2

hence, k12=k2=k33

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For the reaction 2A→ B+3C;if −dAdt=k1A2;dBdt=k2A2;dCdt=k3A2. The correct relation between k1,k2 and k3 is :