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Q.

For the reaction  2HI(g)H2(g)+I2(g) the degree of dissociation (α) of  HI(g) is related to equilibrium constant Kp by the expression

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a

1+2kp2

b

2kp1+2kp

c

2kp1+2kp

d

1+2kp2

answer is C.

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Detailed Solution

2HIH2+I2 

initial                                          1                     0            0at  equilibrium          1α           α2        α2    

Partial pressum  =χ×ptotal

Kp=PH2×PI2PHI2,Hence,Kp=[(α2)PT]2[(1α)2.PT2],

PH2=(α2)PTPI2=(α2)PTPHI=(1α)PT
By solving above equation  α=2Kp1+2Kp

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