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Q.

For the reaction AB

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INCORRECT statement about this is 

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a

At the extent of reaction ‘z’, ΔG=0

b

At the extent of reaction ‘x’, QC (reaction quotient) < Equilibrium constant  (kC)

c

From this data we cannot say in how much time reaction reaches equilibrium

d

At the extent of reaction ‘y’, QC>kC

answer is C.

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Detailed Solution

In G Vs ξ graph, slope is ΔG

A) At X, ΔG is –ve. So reaction is spontaneous  (QC<kC)
B) At Y, ΔG  is +ve. So reaction is non-spontaneous (QC>kC)
C) At Z, ΔG is zero but not ΔG
D) There is no relation between Keq and time required to reach equilibrium state.

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