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Q.

For the reaction AB , the rate law expression is  d[A]dt=k[A]1/2. If initial concentration of A is  A0. Which of the following statement is/are correct regarding this reaction?

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a

There is a linear decrease of rate of reaction with time

b

The integrated form of rate expression is  A=Kt2+A0

c

The half life period is  t1/2=2(21)KA0

d

The plot of A  against ‘t’ will be non-linear.

answer is B, C, D.

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Detailed Solution

For  nth order
K=1(n1)t[1[A]n11[A0]n1]
n=1/2
K=2t[[A0][A]]
[A]=Kt2+[A0]
   [A]   vs  t is linear with negative slope
 

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