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Q.

For the reaction  A(g)2B(g), the equilibrium partial pressures of gases A and B are 4 atm and 2atm respectively. If equilibrium mixture is slowly and isothermally compressed to 12 atm, maintaining equilibrium, then the new equilibrium pressure (in atm) of B(g) is

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a

4 atm

b

3 atm

c

8 atm

d

6 atm

answer is A.

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Detailed Solution

A(g)    2B(g)  ;KP=224=1

At new equilibrium, let partial pressue of A(g) = x atm, and partial pressure of B(g) = y atm
Then total pressure = (x+y) = 12 atm  and  KP=y2x=1
Solving for x and y, we get partial pressure of B(g) = 3 atm

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