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Q.

For the reaction $\underset{(s)}{C} + \underset{(g)}{C O_{2}} ⇌ \underset{(g)}{2 C O}$ the partial pressure of $C O_{2}$ and $C O$ are 2.0
and 4atm respectively at equilibrium the $K_{P}$ of $\underset{(g)}{2 C O} ⇌ \underset{(s)}{C} + \underset{(g)}{C O_{2}}$ is x then 32 x
is

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answer is 4.

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Detailed Solution

$\underset{(s)}{C} + \underset{(g)}{C O_{2}} ⇌ \underset{(g)}{2 C O} K_{p} = \frac{{P_{(C O)}}^{2}}{P_{C O_{2}}} = \frac{4^{2}}{2} = 8 \underset{(g)}{2 C O} ⇌ \underset{(s)}{C} + \underset{(g)}{C O_{2}} \begin{array}{l} K_{p} = \frac{1}{K_{P}} = \frac{1}{8} = x \\ 32 x = 32 \frac{1}{8} = 4 \end{array}$

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For the reaction C(s)+CO2(g)⇌2CO(g) the partial pressure of CO2 and CO are 2.0 and 4atm respectively at equilibrium the KP of 2CO(g)⇌C(s)+CO2(g) is x then 32 x is