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Q.

For the reaction : H2(g) + CO2(g)     CO(g)  +  H2O(g), if the initial concentration of 

H2 = CO2 and x moles / litre of hydrogen is consumed at equilibrium, the correct expression of KP is

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a

1+x21 - x2

b

x21 - x2

c

x21 - x2

d

x22 + x2

answer is A.

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Detailed Solution

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                              H2(g) + CO2(g)     CO(g)  +  H2O(g)

Initial conc.               1            1                    0              0

At equilibrium        (1 - x)     (1 - x)               x               x

KP=pCO . pH2OpH2.pCO2  = x.x1-x 1-x=  x21-x2

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