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Q.

For the reaction
i) $A \overset{K_{1}}{\to} P$ ii) $B \overset{K_{2}}{\to} Q$
following observation is made

Where $K_{1}$ and $K_{2}$ are rate constants for respective reactions. If $\frac{K_{1}}{K_{2}} = x \times 10^{- 4}$ then X is

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answer is 6930.

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Detailed Solution

$K_{1} = \frac{0.693}{30} K_{2} = \frac{a}{2 t_{112}} = \frac{2}{2 \times 30} = \frac{1}{30} \frac{K_{1}}{K_{2}} = \frac{0.693}{30} \times 30 = 0.693 = 693 \times 10^{- 4}$

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For the reaction i) A→K1P ii) B→K2Qfollowing observation is made Where K1 and K2 are rate constants for respective reactions. If K1K2=x×10−4 then X is