Q.

For the reaction 
 I+ClO3+H2SO4Cl+HSO4+I2
The correct statement(s) in the balanced equation is/are

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a

Iodide is oxidized 

b

Sulphur is reduced

c

H2O  is one of the products 

d

Stoichiometric coefficient of  HSO4  is 6

answer is A, B, D.

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Detailed Solution

Balancing the chemical equation by half-reaction method.
 I+ClO3+H2SO4 Cl+HSO4+I2
 2I I2+2e×3
 ClO3+6H++6e Cl+3H2OClO3+6I+6H+ 3I2+Cl+3H2O
Adding  6HSO4  to both sides.
 ClO3+6I+6H2SO4 3I2+Cl+6HSO4+3H2O

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For the reaction  I−+ClO3−+H2SO4→Cl−+HSO4−+I2The correct statement(s) in the balanced equation is/are