Q.

For the reaction, I2(g)+Cl2(g)2ICl(g);ΔH=16kJmol1 .
If Kc=80 at 27C, the value of Kp at 127C is_______
[Given log2=0.3,lnx=2.3logx,R=8.3JK1mol1 ]

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answer is 400.

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Detailed Solution

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As  Δng=0,Kp=Kc
 logKp2Kp1=ΔH2.3R[T2T1T1T2]logKp2log80=160002.3×8.3[400300400×300]
 logKp21.9=160002.3×8.31[400300400×300]logKp2=2.5982.6Kp2=400

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For the reaction, I2(g)+Cl2(g)⇌2ICl(g);ΔH=16 kJmol−1 .If Kc=80 at 27∘C, the value of Kp at 127∘C is_______[Given log2=0.3,lnx=2.3logx,R=8.3JK−1mol−1 ]