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Q.

For the reaction

         MnO4+8H++5eMn2++4H2O,E0=1.50V

         MnO2+4H++2eMn2++2H2O,E0=1.23V

         Thus , for the reaction

         MnO4+4H++3eMnO2+2H2O,E0(in V) is

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answer is 1.68.

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Detailed Solution

Electrons involved are different , hence  Enet0E10+E20

        

         But ΔGnet0=ΔG10+ΔG20

         Signs are taken as per required reaction

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For the reaction         MnO4−+8H++5e−→Mn2++4H2O,E0=1.50V         MnO2+4H++2e−→Mn2++2H2O,E0=1.23V         Thus , for the reaction         MnO4−+4H++3e−→MnO2+2H2O,E0(in V) is