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For the reaction, ${PCl}_{3} (g) + {Cl}_{2} (g) ⇌ {PCl}_{5} (g)$ the position of equilibrium can be shifted to the right by

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doubling the volume

increasing the temperature

addition of

{Cl}_{2}

at constant volume

addition of equi molar quantities of

{PCl}_{3}

and

{PCl}_{5}

answer is D.

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Detailed Solution

The chemical equilibrium is

${PCl}_{3} (g) + {Cl}_{2} (g) ⇌ {PCl}_{5} (g)$

The position of equilibrium will shift towards right by the addition of ${Cl}_{2}$ at constant volume. If increase the concentration of reactants forward reaction favors more.

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