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Q.

For the reaction, PCl3(g)+Cl2(g)PCl5(g) the position of equilibrium can be shifted to the right by

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a

doubling the volume     

b

increasing the temperature

c

addition of Cl2  at constant volume

d

addition of equi molar quantities of PCl3  and PCl5       

answer is D.

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Detailed Solution

The chemical equilibrium  is

  PCl3(g)+Cl2(g)PCl5(g)

The position of equilibrium will shift towards right by the addition of Cl2 at constant volume. If increase the concentration of reactants forward reaction  favors more.

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