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Q.

For the reaction system :

2NO(g)+O2(g)2NO2(g) volume is suddenly  reduced to half its value by increasing the pressure on it. If the reaction is of first order with respect to O2 and second order with respect to NO, the rate of reaction will

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a

diminish to one-eighth of  its initial value

b

diminish to one-fourth of  its initial value

c

increase to eight times of its initial value

d

increase to four times of its initial value

answer is C.

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Detailed Solution

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Rate law=k[O2][NO]2

If volume is reduced to half.  Concentrations will become double.

 Rate=k[2O2][2NO]2=8time

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