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For the reaction $large PC{l_{5(g)}}, rightleftharpoons ,PC{l_{3(g)}}, + ,C{l_{2(g)}}$ the forward reaction at constant temperature is favoured by

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Introduction of an inert gas at constant volume

Introduction of PCl₃_(g) at constant volume

Introduction of PCl_5(g) at constant volume

Introduction of Cl_2(g)at constant volume

answer is C.

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Detailed Solution

large PC{l_5}left( g right) rightleftharpoons PC{l_3}left( g right) + C{l_2}left( g right),Delta H = + ve

Forward reaction is endothermic

favoured at high temperature.

Forward reaction involves increase in volume.

favoured at low pressure

Addition of PCl₅ favours forward reaction.

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