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For the reaction using suitable alkyl halide and a suitable nucleophile what will be the correct match for the nucleophile used as per List-I and the solvent being used in List-II?
List-I
List-II
(P)
$M e S^{-}$
(1)
Reacts with $C H_{3} C H_{2} C l$ to give $S N^{2}$ product
(Q)
$N C^{-} + N H_{4} C l$
(2)
Reacts with $C H_{3} C H O$ followed by hydrolysis to give alanine.
(R)
(3)
Reacts with Et–X followed by $N H_{2} N H_{2}$ gives $E t N H_{2}$
(S)
(4)
Reacts with $C H_{3} C H_{2} C l$ followed by acetone to give 2-methyl-but-2-ene

(5)
Reacts with chloro benzene followed by $H_{3} O^{+}$ give aniline.

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$P \to 1; Q \to 4; R \to 5; S \to 3$

$P \to 5; Q \to 4; R \to 3; S \to 1$

$P \to 5; Q \to 2; R \to 1; S \to 4$

$P \to 1; Q \to 2; R \to 3; S \to 4$

answer is A.

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Detailed Solution

Strongly basic nucleophiles (II, III) cannot be used in presence of protic solvents (P, T)
Neutral Nucleophiles (IV) work better in presence of less protic solvents or aprotic solvents

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