Q.

For the reaction, 2Cl(g)Cl2(g), the correct option is 

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a

ΔrH<0  and  ΔrS>0

b

ΔrH<0  and  ΔrS<0

c

ΔrH>0  and  ΔrS<0

d

ΔrH>0  and  ΔrS>0

answer is D.

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Detailed Solution

 In the reaction,  2Cl(g)Cl2(g), the randomness decreases as 2 moles of Cl(g) are converted to 1 mole of Cl2(g), thus, ΔrS<0
Bond formation is always exothermic process, thus ΔrH<0   

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