Q.

For the reaction 2NO2(g)N2O4(g) if  ΔG0=-5.1kJ,KP=8atm-1and partial pressure of NO2,N2O4 are 1.5 atm and 4.5 atm respectively at 25°C The value of ΔG will be (in kJ)

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a

-3.38 kJ

b

-4.69 kJ

c

-5.1 kJ

d

-1.72 kJ

answer is A.

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Detailed Solution

 Re action Quotient =PN2O4PNO22 =4.5(1.5)2 =2 atm-1 ΔG=ΔG0+2.303RTlog(Q) =-5100+2.303×8.314×298×log(2) =-5100 J+1717.46 J =-3.38 kJ

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