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Q.

For the reaction A+2B products (started with concentrations taken in stoichiometric proportion), the experimentally determined rate law is :

d[A]dt=k[A][B]

The half time of the reaction would be:

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a

0.698k

b

0.6932k

c

not defined

d

0.6931/k

answer is C.

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Detailed Solution

Given,

A+2B  Products

a2aax      2a2x

Here,

dxdt=k2(αx) t 1/2=ln22k t1/2=0.6931/k

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