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Q.

For the reaction A+BC , Hence rate law is

S no

[A]

[B]

Rate

1

1.0 M1.0 M0.25 M min-1

2

2.0 M1.0 M0.50 M min-1

3

1.0 M2.0 M0.25 M min-1

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a

K[A][B]1/2

b

K[B]

c

K[A]

d

K[A][B]

answer is C.

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Detailed Solution

detailed_solution_thumbnail

dxdt=k[A]a[B]b

0.25=k[1.0]a[1.0]b …………..(i)

0.50= k[2.0]a[1.0]b…………..(ii)

0.25= k[1.0]a[2.0]b…………..(iii)

Divide values of (ii) by that of (i) and (iii) by that of (i)

2=2a→a=1

1=2b

20=2b→b=0

Thus, dxdt=k[A]

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