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Q.

For the reaction A+BC+2D experimental results were collected for three trials and the data obtained are given below:

Trial[A],M[B],M

Initial rate,

M s-

1

2

3

0.40

0.80

0.40

0.20

0.20

0.40

5.5×104

5.5×104

2.2×103

the correct rate law of the reaction is:

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a

 rate =k[A]0[B]2

b

 rate =k[A][B]2

c

 rate =k[A][B]

d

 rate =k[A][B]0

answer is A.

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Detailed Solution

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Let rate law =k[A]x[B]y. From experiments,

we have:

5.5×104=k[0.4]x[0.2]y                           ..(i)

5.5×104=k[0.8]x0.2y                       …(ii)

2.2×103=k[0.4]x[0.4]y                           …(iii)

From equations (i) and (ii) ,we have :

5.5×1045.5×104=k[0.4]x[0.2]yk[0.8]x[0.2]y;1=0.4p.8x=12x;120=12x.

So, x = 0.

From equation(i) and (iii), we have:

5.5×1042.2×103=k[0.4]x[0.2]yk[0.4]x[0.4]y;14=12y;122=12y

So, y = 2.

Substituting these values in rate law, we get:

rate law :k[A]0[B]2. So, the correct answer is (1).

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