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Q.

For the reaction A + B products, it is observed that : 

1)On doubling the initial concentration of A only, the rate of reaction is also doubled and 

2)On doubling the initial concentrations of both A and B, there is a change by a factor of 8 in the rate of the reaction. The rate of this reaction is given by : 

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a

rate = k [A][B]2

b

rate = k[A]2[B]

c

rate = k[A][B]

d

rate = k [A]2[B]

answer is A.

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Detailed Solution

When concentration A is doubled, rate is doubled. Hence order with respect to A is one. When concentrations of both A and B are doubled, rate increases by 8 times hence order with respect to B is 2.

 rate = k [A]1[B]2

Total order = 1 + 2 = 3

 

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