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Q.

For the reaction, Mx++MnO4  -MO3+  -Mn2++1/2O2, if one mole of MnO4-oxidizes 1.67 moles of Mx+ to MO3-, then the value of ' x ' in the reaction is

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a

5

b

3

c

2

d

1

 

answer is C.

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Detailed Solution

Let us assume oxidation state of M in Mx+ is x

The oxidation state of M in MO3 -is +5. The net change in electrons/oxidation state is 5-x

  Mx+MO31  - mole conversion involves 5-x moles of electrons

The oxidation state of Mn in MnO4-is +7 and in Mn2+ is +2. The net change in electrons/oxidation state is +5

MnO4-Mn2+1 mole conversion involves 5 mole electron

Given that one mole of MnO4 -oxidizes 1.67 moles of Mx to MO3·  -1.67 mole can be written as 5/3

1 mole conversion Mx+MO3 -involves 5-x moles of electrons, then for 5/3 mole involves 5/3(5-x)

Therefore, 53×(5-x)=5

55 gets cancelled

5-x/3=1

5-x=3; x=5-3; x=2

Hence, the correct option is C.

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