Q.

For the reaction N2(g)+O2(g)2NO(g),ΔH=180kJmol1. Which of the following is not true?

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a

The pressure change at constant temperature does not affect the equilibrium constant

b

The volume change at constant temperature does not affect the equilibrium constant

c

The formation of NO is decreased at higher temperature

d

The formation of NO is increased at higher temperature

answer is D.

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Detailed Solution

ΔH positive means the forward direction is the endothermic direction. Increase in temperature would cause the equilibrium to shift in the endothermic direction, i.e. the formation of NO is increased at higher temperature. Pressure changes do not affect equilibrium. Volume changes do not affect equilibrium as Δνg=0.

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