Q.

For the reaction N2O4 2NO2g, the degree of dissociation at equilibrium is 0.2 at 1 atm. Then Kp will be

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a

1/4

b

1/6

c

1/2

d

1/8

answer is C.

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Detailed Solution

Consider the reaction, N2O4 2NO2g

        Initial                    1                 0

At equilibrium           (1-α)           2α

 PNO2=2X0.21+0.2X1=0.41.2=13

PN2O4=1-0.21+0.2X1=0.81.2=23

 Now, At equilibrium,

     KP=[PNO2]2[PN2O4]2=1X1X33X3X2=16

 Hence, the correct answer is option (C) 1/6.

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