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Q.

For the reaction, PCl3(g)+Cl2(g)PCl5(g) the position of equilibrium can be shifted to the right by

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a

addition of Cl2 at constant volume

b

increasing the temperature

c

addition of equi molar quantities of PCl3 and PCl5

d

doubling the volume

answer is D.

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Detailed Solution

The chemical equilibrium is

PCl3(g)+Cl2(g)PCl5(g)The position of equilibrium will shift towards right by the addition of Cl2at constant volume. If increase the concentration of reactants forward reaction favors more.

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For the reaction, PCl3(g)+Cl2(g)→PCl5(g) the position of equilibrium can be shifted to the right by