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Q.

For the reaction,
PCl5(g)PCl3(g)+Cl2(g)
The forward reaction at constant temperature is favoured by:

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a

introducing an inert gas at constant volume

b

introducing chlorine gas at constant volume

c

introducing an inert gas at constant pressure

d

none of the above

answer is C.

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Detailed Solution

PCl5(g)Mole At. eq. (ax)PCl3(g) x+Cl2(g) x
Now, Kc=x2V(ax)
Addition of inert gas at constant V has no effect on reactions having Δn=0 or Δn0. But addition of inert gas at constant P has effect on reactions having Δn0 and no effect, if Δn=0. The given reaction has Δn0 and thus, only choice (c) is correct. Also, the effect may be drawn as: On addition of inert gas at constant P, volume increases. To have Kc constant, X must increase.

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