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For the reduction of silver ions with copper metal, the standard cell potential is 0.46 V at $25^{o} C$ . The value of standard Gibbs energy ${ΔG}^{o}$ will be

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-44.5 kJ

-89.0 kJ

-89.01 J

-98.0 kJ

answer is A.

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Detailed Solution

$\begin{array}{l} {ΔG}^{o} = - {nE}^{o} F ({For Cu+2Ag}^{+} \to {Cu}^{2 +} + 2 Ag) \\ n = 2 = - 2 \times 0 .46 \times 96500 \\ = - 88788 J = - 89 .0 kJ \end{array}$

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