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Q.

For the reduction of silver ions with copper metal, the standard cell potential was found to be +0.46V at 25°C. The value of standard Gibbs energy, $Δ G^{0}$ will be

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a

– 89.0kJ

b

-44.5kJ

c

-89.0J

d

-98.0KJ

answer is A.

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Detailed Solution

$\begin{array}{l} C u + 2 A g^{+} \to C u^{2 +} + 2 A g \\ Δ G^{0} = - n F E^{0} \\ = - 2 \times 96500 \times 0.46 = - 88.78 k J \end{array}$

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