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Q.

For the reversible reaction \large {N_{2(g)}}\, + \,3{H_{2\left( g \right)}}\, \rightleftharpoons \,2N{H_{3\left( g \right)}} at 5000C. The value of Kp is 1.44×10-5, when partial pressure is measured in atmospheres. The corresponding value of Kc with concentration in mol L-1 is

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a

\frac{{1.44\, \times \,{{10}^{ - 5}}}}{{{{\left( {0.082 \times 500} \right)}^{ - 2}}}}

 

b

\frac{{1.44\, \times \,{{10}^{ - 5}}}}{{{{\left( {8.314 \times 773} \right)}^{ - 2}}}}

 

c

\frac{{1.44\, \times \,{{10}^{ - 5}}}}{{{{\left( {0.082 \times 500} \right)}^2}}}

 

d

\frac{{1.44\, \times \,{{10}^{ - 5}}}}{{{{\left( {0.082 \times 773} \right)}^{ - 2}}}}

 

answer is D.

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Detailed Solution

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Kp = KcRTng

Kc KpRTng

1.44×10-50.082×773-2

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