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Q.

For the reversible reaction (XnY), from the following graph, if rate constant of backward reaction is 10 unit, the rate of forward reaction at (t=0), is “P” (M/minute), then the value of “P”  is ______

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a

16.250

b

4.0625

c

8.125

d

32.500

answer is A.

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Detailed Solution

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              xnyInitial               1.3       0Equilibrium(1.3a)na             0.8M    1.0M               1.3a=0.8a=0.5na=1.0n(0.5)=1.0n=2

Kc=[y]n[x]1=(1.0)2(08)1=10.8=108=1.25

Kc=KfKbKf=(Kc×Kb)=1.25×10=12.5,  Kf=12.5                 rf=Kf×(X)1=(12.5×1.3)               rf=16.25M/ minute

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