Q.

For this first-order isomerization reaction, CH3NCCH3CN, how do the properties of the reaction in the table below vary as the reaction proceeds?

Rate of reaction

ΔCH3NC]Δt,M81

Half-life, (s)
(P) remains the samedecreases
(Q) decreasesremains the same
(R) remains the sameremains the same
(S) decreasesdecreases

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a

S

b

p

c

R

d

Q

answer is B.

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Detailed Solution

For first-order isomerization reaction, CH3NCCH3CN rate of reaction decreases while the half life remains same. Because the concentration of reactant lowers and the concentration of products increases as the reaction moves forward.

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