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Q.

For two reactions : R-I and R-II the rate constants at 300 K and 320 K are 0.1 sec1 and 0.3 sec1 respectively (for R-I) and 0.2 sec1 and 0.8 sec1 (for R-II}. Which of the options regarding activation energy is correct?

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a

Activation energies for both the reactions is same.

b

Activation energy for second reaction is 43 times  as that of first reaction.

c

Activation energy for first reaction is more.

d

Activation energy for second reaction is more.

answer is C.

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Detailed Solution

lnk2k1=EaR1T11T2

lnk2k1lnk2k1=EaEa

Ea>Ea

So, we can says that Activation energy for second reaction is more.

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