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Q.

For which of the following processes, ΔS  is negative

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a

O2(g,1 atm)O2(g,2 atm)

b

N2(g)2N(g)

c

C(Dimond)C(Graphite)

d

Heating of an iron rod

answer is C.

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Detailed Solution

In option A, B and D entropy is increasing where as in C option when pressure is increased O2  molecules come closer to each other hence entropy decreases  ΔS<0

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For which of the following processes, ΔS  is negative