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Q.

 For which of the following, the pH of solution is 11?
 

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a

0.001M KCl

b

0.001MCH3COOH

c

0.001NBa(OH)2

d

 0.001M HCl

answer is D.

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Detailed Solution

 Given data: It is given to find the pH of the solution.

Explanation:Ba(OH)2 assuming it to be completely 
BaOH2Ba2++2OHaq-
Since BaOH2 is completely ionized, one mole of BaOH2 gives 2 moles of OH- ions.
Therefore, OH-= 2 BaOH2 = 2 × 0.001=0.002M
H3O+=KwOH- 1×10-140.002=5×10-12
pH=-logH3O+=-log5×10-12=-log5+log10-12
0.699-12=11.301


Hence, the correct option is (D).

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