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Q.

For which one of the following reactions, G decreases with increasing the temperature

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a

2C(s) + O2(g) → 2CO(g)

b

4Cu(s) + O2(g) → 2Cu2O(s)

c

2Zn(s) +O2(g) → 2ZnO(s)

d

2CO(g) + O2(g) → 2CO2(g)

answer is C.

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Detailed Solution

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For oxidation of carbon to carbon monoxide, H is negative and S is positive due to increase in number of gas molecules. As result, for oxidation of carbon to carbon monoxide, G decreases with increasing temperature. Hence Go vs T plot is a straight line with negative slope for the oxidation of carbon to carbon monoxide.

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