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Q.

For which one of the following reactions, the graph of G against T is almost horizontal to temperature axis

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a

C(s) + O2(g) → CO2(g)

b

2C(s) + O2(g) → 2CO(g)

c

CO(g) + O2(g) → 2CO2(g)

d

2Mg(s) + O2(g) → 2MgO(s)

answer is A.

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Detailed Solution

G=H-TS 

H and G almost remain constant with temperature. so G varies with temperature.

Case-1: when S=0, G is unaffected by T.

Case-2: when S=-ve, G increases with increase in T.

Case-3: when S=+ve, G decreases with increase in T.

C(s)+O2(g) CO2(g) , S=0

G is unaffected by T

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