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Q.

For which one of the following system ΔE<ΔH

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a

2SO2(g)+O2(g)2SO

b

N2(g)+O2(g)2NO

c

2NH3(g)N2(g)+3H2(g)

d

H2(g)+I2(g)2HI

answer is C.

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Detailed Solution

The first law of thermodynamics represents the conservation of energy which states that energy can neither be created nor be destroyed it can only change forms.

We know, ΔH=ΔE+ΔnRT

Where, ΔH is the enthalpy change, ΔE is the internal energy change and Δn is the number of gaseous moles of product - number of gaseous moles of reactant.

When Δn>0,ΔH>ΔE

And when Δn<0,ΔH<ΔE

Considering the equation, 2NH3(g)N2(g)+3H2(g)

Here, Δn=3+1-2=2 which is> 0 .

Hence, ΔE<ΔH is this reaction.

Therefore, option (C) is correct.

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