Q.

Formation of a solution from two components can be considered as
(i) Pure solvent  separated solvent molecules, H1
(ii) Pure solute  separated solute molecules, H2
(iii) Separated solvent & solute molecules + solution, H3
Solution so formed will be ideal if

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a

ΔHsoln =ΔH3ΔH1ΔH2

b

ΔHsoln =ΔH1+ΔH2+ΔH3

c

ΔHsoln=ΔH1ΔH2ΔH3

d

ΔHsoln =ΔH1+ΔH2ΔH3

answer is B.

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Detailed Solution

For an ideal solution, ΔHmixing = 0
ΔH=ΔH1+ΔH2+ΔH3 (According to Hess's law)
i.e., for ideal solutions, there is no change in magnitude of the attractive forces in the two components present.

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