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Q.

Formation of α and β methyl glucosides by glucose on heating with CH3OH in presence of dry HCl gas indicates the presence of a/ an

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a

Aldehyde group

b

CH2OH group

c

Hemiacetal group

d

Acetal group

answer is A.

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Detailed Solution

The reaction discussed above is-

C6H12O6+CH3OHα-C6H11O6CH3+β-C6H11O6CH3

The structure of glucose is cyclic i.e

 

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Here the shown number 1 carbon in the structure of glucose is chiral carbon ( carbon which has all 4 different valencies) and it is chiral due to the presence of an aldehydic group due to which we get a product with two different configurations otherwise the hydroxy group is there at many carbons so aldehyde group is responsible for configurations.

Hence option A is the correct answer.

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